REACTIONS OF DIBORON TETRAHALIDES WITH SOME UNSATURATED ORGANOMETALLIC COMPOUNDS

被引：17

作者：

COYLE, TD

RITTER, JJ

机构：

[1] Inorganic Chemistry Section, National Bureau of Standards, Washington

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1968年 / 12卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)93848-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetrachloro- and tetrafluorodiborane(4) add to the double bond in a number of vinyl derivatives of boron, carbon, silicon, germanium, and tin to form 1,2-bis(dihaloboryl)ethyl derivatives. Most of the compounds are stable in vacuo at temperatures in excess of 150°. Tetrachlorodiborane(4) undergoes addition considerably more readily than does tetrafluorodiborane(4). Relative rates of addition have been determined and shown to be markedly dependent on the nature of the substituent on the vinyl group. © 1968.

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页码：269 / &

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