SYNTHESIS AND CHARACTERIZATION OF ANISOMETRIC COBALT NANOCLUSTERS

被引：104

作者：

GIBSON, CP

PUTZER, KJ

机构：

[1] Department of Chemistry, University of Wisconsin, Oshkosh

来源：

SCIENCE | 1995年 / 267卷 / 5202期

关键词：

D O I：

10.1126/science.267.5202.1338

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Sonication of aqueous Co2+ and hydrazine resulted in the formation of anisometric (disk-shaped) cobalt nanoclusters that averaged about 100 nanometers in width and 15 nanometers in thickness. Electron diffraction from single particles revealed that they were oriented (001) crystals that conformed to a trigonal or hexagonal unit cell four times the size of the cell adopted by bulk alpha-cobalt. Lorentz microscopy indicated that these were single-magnetic domain particles, with the axis of magnetization located in the (101) plane, offset at some appreciable angle from the [001] axis.

引用

页码：1338 / 1340

页数：3

共 24 条

[1]

Audrieth LF, 1951, CHEM HYDRAZINE

[2] GRANULAR COBALT IN A METALLIC MATRIX [J].