MAGNETIC SPIN EFFECTS ON PHOTOOXIDATION QUANTUM YIELDS OF RU-II-TRIS(BIPYRIDINE) TYPE COMPLEXES IN MAGNETIC-FIELDS UP TO 17.5 TESLA

被引：29

作者：

BURSSNER, D ^{[1
]}

WOLFF, HJ ^{[1
]}

STEINER, UE ^{[1
]}

机构：

[1] UNIV KONSTANZ,FAK CHEM,D-78434 CONSTANCE,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 17期

关键词：

D O I：

10.1002/anie.199417721

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spin‐control of the rate of electron transfer processes can also be detected in systems with very strong spin‐orbit coupling such as in the ruthenium complex [Ru(bpy)3]2+, bipy = 2, 2′‐bipyridine. From the influence of an external magnetic field, which was varied continuously up to the extremely high fields of 17.5 Tesla, the kinetic details of the very fast photooxidation of [Ru(bpy)3]2+ by methylviologen were determined quantitatively. Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1772 / 1775

页数：4

共 30 条

[1]

BALZANI V, 1991, SUPRAMOLECULAR PHOTO

[2]

BANCI L, 1991, NUCLEAR ELECTRON REL

[3] THE EFFECT OF MAGNETIC-ANISOTROPY ON THE LONGITUDINAL NUCLEAR-RELAXATION TIME IN PARAMAGNETIC SYSTEMS [J].