SOLUBILITIES FOR THE 2 TERNARY-SYSTEMS WATER PLUS LITHIUM BROMIDE PLUS LITHIUM IODIDE AND WATER PLUS LITHIUM-CHLORIDE PLUS LITHIUM-NITRATE AT VARIOUS TEMPERATURES

被引:31
作者
IYOKI, S
IWASAKI, S
KURIYAMA, Y
UEMURA, T
机构
[1] Department of Chemical Engineering, Faculty of Engineering, Kansai University, Suita
关键词
D O I
10.1021/je00011a016
中图分类号
O414.1 [热力学];
学科分类号
摘要
Solubilities for the water + lithium bromide + lithium iodide (salt mole ratio 4:1) and the water + lithium chloride + lithium nitrate (salt mole ratio 2.8:1) systems were measured by means of a visual polythermal method from 277.75 to 415.15 K and from 284.85 to 351.75 K, respectively. The transition point for the water + lithium bromide + lithium iodide system existed at 65.3 mass % salts and 293.85 K and at 54.2 mass % salts and 295.75 K for the water + lithium chloride + lithium nitrate system. Two solid-liquid phases for these two ternary systems were stable below and above the individual transition point. Two least-squares regression equations as a function of absolute temperatures were obtained from the individual measured solubility data for these two ternary systems. The maximum and average absolute deviations of the calculated values from the individual experimental data were 0.29 and 0.10 % for the water + lithium bromide + lithium iodide system and 0.93 and 0.32% for the water + lithium chloride + lithium nitrate system, respectively.
引用
收藏
页码:396 / 398
页数:3
相关论文
共 50 条
[21]   Thermodynamic properties of the ternary system potassium bromide plus lithium bromide plus water at 25°C [J].
Yan, WD ;
Zhang, R ;
Han, SJ .
JOURNAL OF SOLUTION CHEMISTRY, 2001, 30 (02) :193-200
[22]   Liquid-liquid-solid equilibria for ternary systems water plus lithium chloride plus pentanols [J].
Gomis, V ;
Ruiz, F ;
Boluda, N ;
Saquete, MD .
FLUID PHASE EQUILIBRIA, 2004, 215 (01) :79-83
[23]   Electrical conductivity, viscosity, and sound velocity of lithium bromide plus lithium nitrate plus acetamide melt systems [J].
Kalita, G ;
Sarma, RG ;
Mahiuddin, S .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1999, 44 (02) :222-226
[24]   Solubilities, Vapor Pressures, and Heat Capacities of the Water + Lithium Bromide + Lithium Nitrate + Lithium Iodide + Lithium Chloride System [J].
K.-K. Koo ;
H.-R. Lee ;
S. Jeong ;
Y.-S. Oh ;
D.-R. Park ;
Y.-S. Baek .
International Journal of Thermophysics, 1999, 20 :589-600
[25]   Thermal property measurements and enthalpy calculation of the lithium bromide plus lithium iodide+1,3-propanediol plus water system [J].
Kim, JS ;
Lee, HS ;
Lee, H .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2000, 21 (06) :1407-1418
[26]   Surface tensions and differential enthalpies of dilution of the lithium bromide plus lithium iodide+1,3-propanediol plus water system [J].
Kim, KS ;
Lee, H .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2002, 47 (01) :98-101
[27]   Crystallization temperature, vapor pressure, density and viscosity of lithium bromide plus lithium iodide plus ethylene glycol plus water system for absorption refrigerators for automotive use [J].
Inada, Takaaki ;
Tomita, Hiroyuki ;
Takemura, Fumio ;
Tsubouchi, Osamu ;
Hihara, Eiji .
INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID, 2019, 100 :274-283
[28]   Vapor-liquid equilibrium of ammonia plus lithium nitrate plus water and ammonia plus lithium nitrate solutions from (293.15 to 353.15) K [J].
Libotean, Simona ;
Salavera, Daniel ;
Valles, Manel ;
Esteve, Xavier ;
Coronas, Alberto .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (03) :1050-1055
[29]   Densities, Viscosities, and Heat Capacities of Ammonia plus Lithium Nitrate and Ammonia plus Lithium Nitrate plus Water Solutions between (293.15 and 353.15) K [J].
Libotean, Simona ;
Martin, Andreu ;
Salavera, Daniel ;
Valles, Manel ;
Esteve, Xavier ;
Coronas, Alberto .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (10) :2383-2388
[30]   Vapor pressures, densities, and viscosities of the (water plus lithium bromide plus sodium formate) system and (water plus lithium bromide plus potassium formate) system. (vol 48, pg 18, 2003) [J].
De Lucas, A ;
Donate, M ;
Rodríguez, JF .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2003, 48 (03) :756-756