Tetrakis(mu-2-phenylacetato-kappa O-2:O ')bis{[4-(dimethylamino)pyridine-kappa N ']cobalt(II)}

被引:3
作者
Benslimane, Meriem [1 ]
Redjel, Yasmine Kheira [1 ]
Denes, Georges [2 ]
Merazig, Hocine [1 ]
机构
[1] Univ Constantine 1, Fac Sci Exactes, Dept Chim, Unite Rech Chim Environnement & Moleculaire Stru, Constantine 25000, Algeria
[2] Concordia Univ, Dept Chem & Biochem, Montreal, PQ, Canada
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词
D O I
10.1107/S1600536813023258
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Co-2(C8H7O2)(4)(C7H10N2)(2)], crystallizes as a centrosymmetric dimer containing two Co-II atoms bridged by four bidentate phenylacetate ligands in syn-syn bridging modes. Each Co-II atom is five-coordinated by four O atoms from four different carboxylate ligands and the ring N atom of a 4-(dimethylamino) pyridine unit, generating a distorted square-pyramidal geometry in which the four O atoms form the basal plane and the N atom occupies the axial position. In the crystal, C-H center dot center dot center dot O interactions link the dinuclear complex molecules into a three-dimensional network.
引用
收藏
页码:M517 / +
页数:10
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