CHEMOSELECTIVE METHYLTRIOXORHENIUM(VII)-CATALYZED SULFOXIDATIONS WITH HYDROGEN-PEROXIDE

被引：80
作者：
ADAM, W
MITCHELL, CM
SAHAMOLLER, CR
机构：
[1] Institute of Organic Chemistry, University of Würzburg, D-97074 Würzburg, Am Hubland
来源：
TETRAHEDRON | 1994年 / 50卷 / 46期
关键词：
D O I：
10.1016/S0040-4020(01)89321-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The selective oxidation of sulfides to sulfoxides by hydrogen peroxide under methyltrioxorhenium(VII) catlysis was examined; a high selectivity of sulfoxide over sulfone was achieved, except in the presence of water, which enhanced sulfone formation.
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页码：13121 / 13124
页数：4
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