NICKEL-CATALYZED REACTIONS OF 3,4-BENZO-1,1,2,2-TETRAETHYL-1,2-DISILACYCLOBUTENE

被引：31

作者：

ISHIKAWA, M

SAKAMOTO, H

OKAZAKI, S

NAKA, A

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Hiroshima University, Hiroshima, 724, Higashi

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 439卷 / 01期

关键词：

D O I：

10.1016/0022-328X(92)80049-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 3,4-benzo-1,1,2,2-tetraethyl-1,2-disilacyclobutene (1) with benzene in the presence of a catalytic amount of Ni(PEt3)4 afforded 1-diethylphenylsilyl-2-(diethylsilyl)benzene, while reaction with diphenylacetylene and benzaldehyde gave the respective products arising from insertion of 1 into an Si-Si bond.

引用

页码：19 / 21

页数：3

共 7 条

[1] SILYLIRON CARBONYL-COMPLEXES IN ORGANIC-SYNTHESIS - SELECTIVE CONVERSION OF NITRILES INTO N,N-BIS(SILYL) ENAMINES [J].