THE DYNAMIC JAHN-TELLER EFFECT IN THE BENZENE CATION - ROTATIONALLY RESOLVED ZEKE PHOTOELECTRON-SPECTRA OF THE NU-6(E2G) MODE

被引：29

作者：

LINDNER, R ^{[1
]}

SEKIYA, H ^{[1
]}

MULLERDETHLEFS, K ^{[1
]}

机构：

[1] KYUSHU UNIV,INST ADV MAT STUDY,FUKUOKA 812,JAPAN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 09期

关键词：

D O I：

10.1002/anie.199313641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A textbook example of the dynamic Jahn–Teller effect is provided by the Jahn‐Teller components of the v6 mode of the benzene cation. They were resolved to the rotational level for the first time by zero kinetic energy (ZEKE) photoelectron spectroscopy. The picture on the right shows the ZEKE spec‐trum of the 61(j= ± 1/2) band of the electronic ground state of the benzene cation via the intermediate state S1 61(J′ =1, K′ =1, +l). (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1364 / 1366

页数：3

共 27 条

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