MOLECULAR QUANTUM BEAT SPECTROSCOPY

被引：49

作者：

BITTO, H

HUBER, JR

机构：

[1] Physikalisch-Chemisches Institut der Universität Zürich, CH-8057 Zürich

来源：

OPTICS COMMUNICATIONS | 1990年 / 80卷 / 02期

关键词：

D O I：

10.1016/0030-4018(90)90382-4

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

The present account of high-resolution molecular quantum beat spectroscopy emphasizes the versatility of this powerful Doppler-free method. Illustrations are drawn from work on the six-atomic molecule propynal carried out in the authors' laboratory. Examples of anisotropic Zeeman, Stark and hyperfine quantum beats, of isotropic molecular quantum beats and of multi-level quantum beats are discussed with regard to intramolecular relaxation dynamics and the determination of structural parameters such as nuclear hyperfine constants, electric dipole moments, spin-orbit matrix elements and asymmetry-splittings.

引用

页码：184 / 198

页数：15

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