PLATINUM-COMPLEX-CATALYZED DEHYDROGENATIVE DOUBLE SILYLATION OF ACETYLENES, DIENES, AND OLEFINS WITH BIS(HYDROSILANE) COMPOUNDS

被引：99
作者：
TANAKA, M
UCHIMARU, Y
LAUTENSCHLAGER, HJ
机构：
[1] National Chemical Laboratory for Industry, Tsukuba
来源：
ORGANOMETALLICS | 1991年 / 10卷 / 01期
关键词：
D O I：
10.1021/om00047a010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Acetylenes, dienes, and olefins underwent dehydrogenative double silylation with bis(hydrosilane) species in the presence of platinum complex catalysts to give disilacyclic compounds in good yields.
引用
收藏
页码：16 / 18
页数：3
相关论文
共 28 条
[1]   RING-INSERTION AND RING-OPENING REACTIONS OF OCTAETHYLCYCLOTETRASILANE [J].
CARLSON, CW ;
WEST, R .
ORGANOMETALLICS, 1983, 2 (12) :1801-1807
[2]  
Corey J. Y., 1988, SILICON CHEM
[3]   SOME PLATINUM COMPLEXES CONTAINING CHELATING BIS(SILYL) LIGANDS [J].
EABORN, C ;
METHAM, TN ;
PIDCOCK, A .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 63 (DEC16) :107-117
[4]   PLATINUM COMPLEX-CATALYZED DEHYDROGENATIVE MONOSILYLATION OF ALKENES WITH DISILANES [J].
HAYASHI, T ;
KAWAMOTO, AM ;
KOBAYASHI, TA ;
TANAKA, M .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (07) :563-564
[5]   PLATINUM-COMPLEX-CATALYZED DOUBLE SILYLATION OF ETHYLENE AND NORBORNENE WITH DISILANES [J].
HAYASHI, T ;
KOBAYASHI, T ;
KAWAMOTO, AM ;
YAMASHITA, H ;
TANAKA, M .
ORGANOMETALLICS, 1990, 9 (01) :280-281
[6]   REACTIVITY OF CIS-BIS(DIMETHYLPHENYLSILYL)BIS(PHOSPHINE)PLATINUM COMPLEXES TOWARD UNSATURATED-COMPOUNDS RELEVANT TO DOUBLE SILYLATION [J].
KOBAYASHI, T ;
HAYASHI, T ;
YAMASHITA, H ;
TANAKA, M .
CHEMISTRY LETTERS, 1989, (03) :467-470
[7]   PALLADIUM CATALYZED DOUBLE SILYLATION OF BIS(TRIMETHYLSILYL)BUTADIYNE BY MEANS OF DISILANES [J].
KUSUMOTO, T ;
HIYAMA, T .
TETRAHEDRON LETTERS, 1987, 28 (16) :1807-1810
[8]   ADDITION OF CHLORODISILANES TO 1,3-BUTADIENES IN THE PRESENCE OF TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0) - FACILE ROUTE TO (Z)-1,4-BIS(CHLOROSILYL)BUT-2-ENES [J].
MATSUMOTO, H ;
SHONO, K ;
WADA, A ;
MATSUBARA, I ;
WATANABE, H ;
NAGAI, Y .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 199 (02) :185-193
[9]   ADDITION OF CHLORODISILANES TO ACETYLENE CATALYZED BY TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(O) - A FACILE ROUTE TO (Z)-1,2-BIS(CHLOROSILYL)ETHENES [J].
MATSUMOTO, H ;
MATSUBARA, I ;
KATO, T ;
SHONO, K ;
WATANABE, H ;
NAGAI, Y .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 199 (01) :43-47
[10]   (PPH3)3RHCL-CATALYZED HYDROSILYLATION OF UNSATURATED MOLECULES BY 1,2-BIS(DIMETHYLSILYL)ETHANE - UNPRECEDENTED RATE DIFFERENCE BETWEEN 2 SI-H BONDS [J].
NAGASHIMA, H ;
TATEBE, K ;
ISHIBASHI, T ;
SAKAKIBARA, J ;
ITOH, K .
ORGANOMETALLICS, 1989, 8 (10) :2495-2496
123