PREPARATION AND CRYSTAL-STRUCTURE OF BIS(CYCLOHEXYLAMMONIUM)HEPTASULFIDE-CENTER-DOT-CYCLOHEXYLAMINE, [C6H11NH3]S-2(7)CENTER-DOT-C6H11NH2

被引：5
作者：
MULLER, C
BOTTCHER, P
机构：
[1] TECH UNIV DRESDEN,LEHRSTUHL 1,INST ANORGAN CHEM,D-01062 DRESDEN,GERMANY
[2] UNIV DUSSELDORF,LEHRSTUHL 2,INST ANORGAN CHEM & STRUKT CHEM,D-40225 DUSSELDORF,GERMANY
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1995年 / 50卷 / 11期
关键词：
CRYSTAL STRUCTURE; POLYCHALCOGENIDES;
D O I：
10.1515/znb-1995-1108
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of cyclohexylamine, sulfur, and hydrogen sulfide in a 2:1-mixture of ethanol and water gives a red cyclohexylammonium polysulfide solution. Orange crystals of the title compound can be obtained by slow cooling. The compound crystallizes in the centrosymmetric triclinic space group P (1) over bar. The lattice constants are a = 8.478(7) Angstrom; b = 11.97(1) Angstrom, c = 14.141(8) Angstrom, alpha = 102.60(6)degrees, beta = 90.53(5)degrees, gamma = 90.43(7)degrees. The S-7(2-)-chain has an uncommon cis-trans-cis conformation with a sequence of the signs of torsion angles of (+--+) and (-++-).
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页码：1623 / 1626
页数：4
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