MORPHINE RECOGNITION BY A PORPHYRIN CYCLOCHOLATE MOLECULAR BOWL

被引：67

作者：

BONARLAW, RP ^{[1
]}

MACKAY, LG ^{[1
]}

SANDERS, JKM ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CTR MOLEC RECOGNIT,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 05期

关键词：

D O I：

10.1039/c39930000456

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A molecular bowl has been prepared by constructing a metalloporphyrin on one face of a tetrameric cyclocholate; the bowl selectively binds morphine by a combination of nitrogen-metal ligation and hydrogen bonding.

引用

页码：456 / 458

页数：3

共 14 条

[1]

ANDERSON HL, 1992, SUPRAMOL CHEM, P359

[2] MOLECULAR RECOGNITION .5. MOLECULAR RECOGNITION OF SUGARS VIA HYDROGEN-BONDING INTERACTION WITH A SYNTHETIC POLYHYDROXY MACROCYCLE [J].

AOYAMA, Y ;

TANAKA, Y ;

SUGAHARA, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (14) :5397-5404

[3] DIASTEREOSELECTIVE AND ENANTIO-SELECTIVE BINDING OF OCTYL GLUCOSIDES BY AN ARTIFICIAL RECEPTOR [J].

BHATTARAI, KM ;

BONARLAW, RP ;

DAVIS, AP ;

MURRAY, BA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (10) :752-754

[4] NEW PROCEDURES FOR SELECTIVELY PROTECTED CHOLIC-ACID DERIVATIVES - REGIOSELECTIVE PROTECTION OF THE 12-ALPHA-OH GROUP, AND TERT-BUTYL ESTERIFICATION OF THE CARBOXYL GROUP [J].

BONARLAW, RP ;

DAVIS, AP ;

SANDERS, JKM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1990, (08) :2245-2250

[5] CYCLOCHOLATES - SYNTHESIS AND ION BINDING [J].

BONARLAW, RP ;

SANDERS, JKM .

TETRAHEDRON LETTERS, 1992, 33 (15) :2071-2074

[6] SYNTHESIS, BINDING-PROPERTIES AND SELF-FUNCTIONALIZATION OF A STEROID-CAPPED PORPHYRIN [J].

BONARLAW, RP ;

SANDERS, JKM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (08) :574-577

[7] BASKET-SHAPED MOLECULAR CAVITY-CONTAINING DONOR CENTERS - SYNTHESIS, STRUCTURE, PROPERTIES [J].

BREITENBACH, J ;

RISSANEN, K ;

WOLF, UU ;

VOGTLE, F .

CHEMISCHE BERICHTE, 1991, 124 (10) :2323-2327

[8] CHIRAL RECOGNITION IN CLEFTS AND CYCLOPHANE CAVITIES SHAPED BY THE 1,1'-BINAPHTHYL MAJOR GROOVE [J].

CASTRO, PP ;

GEORGIADIS, TM ;

DIEDERICH, F .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (25) :5835-5838

[9]

CRAM DJ, 1992, J AM CHEM SOC, V114, P7749

[10] HIGHLY SELECTIVE BINDING OF SIMPLE PEPTIDES BY A C3 MACROTRICYCLIC RECEPTOR [J].

HONG, JI ;

NAMGOONG, SK ;

BERNARDI, A ;

STILL, WC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (13) :5111-5112

← 1 2 →