N-(2,3-Dimethylphenyl)-2-nitrobenzene-sulfonamide

被引:2
作者
Chaithanya, U. [1 ]
Foro, Sabine [2 ]
Gowda, B. Thimme [1 ]
机构
[1] Mangalore Univ, Dept Chem, Mangalagangothri 574199, Karnataka, India
[2] Tech Univ Darmstadt, Inst Mat Sci, D-64287 Darmstadt, Germany
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词
data-to-parameter ratio = 15.3; mean ̄(C-C) = 0.006 Å; R factor = 0.062; single-crystal X-ray study; T = 293 K; wR factor = 0.164;
D O I
10.1107/S1600536812042845
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
There are two independent molecules in the asymmetric unit of the title compound, C14H14N2O4S. The N-H bonds are syn to the ortho-nitro groups in the sulfonyl benzene rings and anti to the methyl groups in the aniline benzene rings. The molecules are twisted at the S-N bonds with torsion angles of -60.4 (3) and 58.8 (3)degrees in the two molecules. The dihedral angles between the planes of the sulfonyl and the anilino benzene rings are 53.67 ( 8) and 56.99 (9)degrees. The amide H atoms of both molecules are involved in an intramolecular hydrogen bond, generating an S(7) motif. In the crystal, pairs of N-H center dot center dot center dot O(S) hydrogen bonds link like molecules into inversion dimers.
引用
收藏
页码:O3188 / +
页数:11
相关论文
共 13 条
  • [1] Preparation and characterization of a series of thiourea derivatives as phase change materials for thermal energy storage
    Alkan, Cemil
    Tek, Yusuf
    Kahraman, Derya
    [J]. TURKISH JOURNAL OF CHEMISTRY, 2011, 35 (05) : 769 - 777
  • [2] PATTERNS IN HYDROGEN BONDING - FUNCTIONALITY AND GRAPH SET ANALYSIS IN CRYSTALS
    BERNSTEIN, J
    DAVIS, RE
    SHIMONI, L
    CHANG, NL
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (15) : 1555 - 1573
  • [3] A triclinic polymorph of benzanilide: disordered molecules form hydrogen-bonded chains
    Bowes, KF
    Glidewell, C
    Low, JN
    Skakle, JMS
    Wardell, JL
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2003, 59 : O1 - O3
  • [4] N-(2-Methylphenyl)-2-nitrobenzene-sulfonamide
    Chaithanya, U.
    Foro, Sabine
    Gowda, B. Thimme
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2649 - +
  • [5] Kinetics of oxidation of acidic amino acids and their monoamides by N-chloroarylsulphonamides in aqueous acidic medium
    Gowda, BT
    Shetty, M
    [J]. JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 2004, 17 (10) : 848 - 864
  • [6] Infrared and NMR spectra of arylsulphonamides, 4-X-C6H4SO2NH2 and i-X, j-YC6H3SO2NH2 (X = H; CH3; C2H5; F; Cl; Br; I or NO2 and i-X, j-Y = 2,3-(CH3)2; 2,4-(CH3)2; 2,5(CH3)2; 2-CH3, 4-Cl; 2-CH3, 5-Cl; 3-CH3, 4-Cl; 2,4-Cl2 or 3,4-Cl2)
    Gowda, BT
    Jyothi, K
    D'Souza, JD
    [J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 2002, 57 (12): : 967 - 973
  • [7] GOWDA BT, 1994, Z NATURFORSCH A, V49, P695
  • [8] Oxford Diffraction, 2009, CRYSALIS CCD CRYSALI
  • [9] A monoclinic polymorph of N-(3-chlorophenyl)benzamide
    Saeed, Aamer
    Arshad, Muhammad
    Simpson, Jim
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O2808 - U130
  • [10] 3-Acetyl-1-(2-methylphenyl) thiourea
    Shahwar, Durre
    Tahir, M. Nawaz
    Chohan, Muhammad Mansha
    Ahmad, Naeem
    Raza, M. Asam
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1160 - +