IRREVERSIBLE BINDING OF DIOXYGEN AND OTHER GASES TO A HALF-SANDWICH RUTHENIUM(II) COMPLEX - X-RAY STRUCTURE OF [RU(ETA-2-O2)(ETA-5-C5ME5)(PH2PCH2CH2PPH2)]PF6

被引：62

作者：

KIRCHNER, K ^{[1
]}

MAUTHNER, K ^{[1
]}

MEREITER, K ^{[1
]}

SCHMID, R ^{[1
]}

机构：

[1] VIENNA TECH UNIV,INST MINERAL CRYSTALLOG & STRUCT CHEM,A-1060 VIENNA,AUSTRIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 11期

关键词：

D O I：

10.1039/c39930000892

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The half-sandwich compound [Ru(eta5-C5Me5)(dppe)]Cl 1 dagger is shown to coordinate simple in organic gases viz. H-2, Cl2, NO and O2; of these the side-on bonded peroxide [Ru(eta2-O2)(eta5-C5Me5)(dppe)]+ 2 is described in more detail including its X-ray crystal structure.

引用

页码：892 / 894

页数：3

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