REGIOSELECTIVE AND STEREOSPECIFIC SYNTHESIS OF BETA,GAMMA-UNSATURATED CARBOXYLIC-ACIDS USING ALLYLBARIUMS

被引:0
作者
YANAGISAWA, A [1 ]
YASUE, K [1 ]
YAMAMOTO, H [1 ]
机构
[1] NAGOYA UNIV,DEPT APPL CHEM,CHIKUSA,NAGOYA 46401,JAPAN
关键词
D O I
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中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Stereochemically homogeneous (E)- or (Z)-beta,gamma-unsaturated carboxylic acids were easily prepared in good yield by highly alpha-selective carboxylation of allylic barium reagents derived from the corresponding allylic chlorides with carbon dioxide.
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页码:593 / 594
页数:2
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