CROSS-LINKABLE EMULSION POLYMERS BY AUTOXIDATION .2.

被引：11

作者：

CHEN, FB ^{[1
]}

BUFKIN, BG ^{[1
]}

机构：

[1] UNIV SO MISSISSIPPI,DEPT POLYMER SCI,HATTIESBURG,MS 39401

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1985年 / 30卷 / 12期

关键词：

COPOLYMERS - Physical Properties - PLASTICS FILMS - Mechanical Properties - POLYMERS - Oxidation;

D O I：

10.1002/app.1985.070301204

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The physicomechanical properties, molecular weights, glass transition temperatures, and crosslinking mechanisms of fatty acrylate copolymers consisting of unsaturated bonds in the side chain were studied. The kinetics of the crosslinking mechanism of polymer films was analyzed by isothermal differential scanning calorimetry. The crosslinking rate was slow and influenced more by cobalt catalyst than by lead catalyst. The different physical properties displayed by the polymer films with and without catalysts demonstrated the occurrence of autoxidation.

引用

页码：4551 / 4570

页数：20

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