MONO-ETA-CYCLOPENTADIENYL-BENZAMIDINATO COMPOUNDS OF TITANIUM, ZIRCONIUM AND HAFNIUM

被引：49
作者：
CHERNEGA, AN
GOMEZ, R
GREEN, MLH
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 18期
关键词：
D O I：
10.1039/c39930001415
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The new compounds [M(eta-C5R5){eta-R'NC(Ph)NR'}Cl2] [where R'= Me3Si (TMS), and R = H, M = Ti, Zr, H for R = Me,M = Ti or Zr], [Zr(eta-C5R5){(eta-R'NC(Ph)NR'}(CH2Ph)Cl] (R = H, Me), and [Zr(eta-C5R5){eta-R'NC(Ph)NR)(CH2Ph)2] (R = H, Me) are described; the compound [Zr(eta-C5H5){eta-R'C(Ph)R'}Cl2] acts as a cocatalyst for the polymerisation of ethylene and propene.
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页码：1415 / 1417
页数：3
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