AUTOREDUCTION OF COPPER(II) BY A NONCHELATING AMINE LIGAND - SYNTHESIS AND X-RAY STRUCTURE OF TRIS(2,3-DIMETHYLPYRAZINE)DICOPPER(I) PERCHLORATE

被引：38
作者：
TURNBULL, MM [1 ]
PON, G [1 ]
WILLETT, RD [1 ]
机构：
[1] WASHINGTON STATE UNIV,DEPT CHEM,PULLMAN,WA 99164
来源：
POLYHEDRON | 1991年 / 10卷 / 15期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/S0277-5387(00)83808-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of Cu(ClO4)2 with 2,3-dimethylpyrazine (2,3-dmpz) in aqueous solution yields the bright yellow, air-stable, crystalline complex Cu2(2,3-dmpz)3(ClO4)2 (1) in 40% yield. The single-crystal X-ray structure reveals a two-dimensional polymeric lattice of tricoordinate copper(I) atoms bridged by 2,3-dimethylpyrazine ligands.
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页码：1835 / 1838
页数：4
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