1,3-DIOXA-[3]FERROCENOPHANES

被引：19
作者：
HERBERHOLD, M
BRENDEL, HD
机构：
[1] Anorganisch-chemisches Laboratorium der Universität Bayreuth, D-95440 Bayreuth
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 458卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(93)80475-Q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of 1,1'-ferrocenediol, Fe(C5H4OH)2, with dihalides (E'Cl2) in the presence of triethylamine has been used to synthesize the 1,3-dioxa-[3]ferrocenophanes, Fe(C3H4O)2E' (E' = P(t)Bu, As(t)Bu, Sb(t)Bu, BPh). Starting from triphosgene, (Cl3CO)2CO, as a precursor of phosgene (COCl2), the analogous 1,3-dichalcogena-[3]ferrocenophan-2-ones Fe(C5H4O)2CO and Fe(C5H4S)2CO were obtained. All new compounds were characterized by their H-1 and 13 C NMR spectra as well as their mass spectra.
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页码：205 / 209
页数：5
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