STRUCTURE AND MAGNETIC-BEHAVIOR OF A NEW 2-DIMENSIONAL ANTIFERROMAGNETIC MANGANESE(II)-MU-1,3-AZIDO SYSTEM

被引：107

作者：

ESCUER, A

VICENTE, R

GOHER, MAS

MAUTNER, FA

机构：

[1] UNIV ALEXANDRIA,FAC SCI,DEPT CHEM,ALEXANDRIA 21321,EGYPT

[2] GRAZ TECH UNIV,INST PHYS & THEORET CHEM,A-8010 GRAZ,AUSTRIA

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 23期

关键词：

D O I：

10.1021/ic00127a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new two-dimensional manganese system has been characterized from the structural and magnetic point of view. The compound with formula [Mn(4acpy)(2)(N-3)(2)], 4acpy = 4-acetylpyridine, shows an unusually large Mn-Mn intralayer distance close to 6 Angstrom. The azido ligand acts as an end-to-end bridge between the manganese ions. Magnetic susceptibility data between 300 and 4 K indicate antiferromagnetic behavior and susceptibility, and EPR measurements are indicative of long-range order below 28 K.

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页码：5707 / &

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