REACTIONS OF THE METALLABROMOALKANE [MO((CH2)3BR)(CO)3(ETA-C5H5)] AND THE CARBENE COMPLEXES TRANS-[MOI(=C(CH2)3O)(CO)2(ETA-C5H4R)](R=H OR ME) WITH LI(BET3H) - THE SYNTHESIS (R=H OR ME) AND X-RAY STRUCTURE (R=ME) OF [MO(CH(CH2)3O)(CO)2(ETA-C5H4R)] CONTAINING AN UNUSUAL OXYGEN MOLYBDENUM DONOR INTERACTIONH

被引：15

作者：

ADAMS, H ^{[1
]}

BAILEY, NA ^{[1
]}

CAHILL, P ^{[1
]}

ROGERS, D ^{[1
]}

WINTER, MJ ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1986年 / 10期

关键词：

D O I：

10.1039/dt9860002119

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：2119 / 2126

页数：8

共 29 条

[1] REACTIONS OF METALLABROMOALKANES [M((CH2)NBR)(CO)3(ETA-C5H5)] (M=MOORW,N=3OR4) WITH TRANSITION-METAL ANIONS - DIMETALLAALKANE AND CYCLIC CARBENE COMPLEX-FORMATION - CRYSTAL AND MOLECULAR-STRUCTURES OF [(ETA-C5H5)(OC)3MO((CH2)4)MO(CO)3(ETA-C5H5)] AND [(ETA-C5H5)(OC)3MOW(CO)2(C-O-(CH2)2CH2)(ETA-C5H5)] [J].

ADAMS, H ;

BAILEY, NA ;

WINTER, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (02) :273-278

[2] AN UNUSUAL MOLYBDENUM-OXYGEN INTERACTION IN THE PRODUCT FROM REACTION OF MO([CH2]3BR)(CO)3(ETA-C5H4R) (R = H, ME) WITH LIET3BH - SYNTHESIS AND X-RAY STRUCTURE OF MO(CO)2(ETA-2-CH.O.[CH2]2CH2)(ETA-C5H4ME) [J].

ADAMS, H ;

BAILEY, NA ;

CAHILL, P ;

ROGERS, D ;

WINTER, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (15) :831-833

[3]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[4] METAL CYCLIC CARBENE COMPLEXES - A MOLYBDENUM COMPLEX OF 2-OXACYCLOPENTYLIDENE - SYNTHESIS AND X-RAY STRUCTURE OF [MOL(CO)2(C4H6O)(ETA-C5H5)] [J].

BAILEY, NA ;

CHELL, PL ;

MUKHOPADHYAY, A ;

TABBRON, HE ;

WINTER, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (04) :215-217

[5] CYCLIC CARBENE COMPLEXES OF MOLYBDENUM AND TUNGSTEN - CRYSTAL AND MOLECULAR-STRUCTURE OF [MOL(CO)2(CO(CH2)2CH2)(ETA-C5H5)] [J].

BAILEY, NA ;

CHELL, PL ;

MANUEL, CP ;

MUKHOPADHYAY, A ;

ROGERS, D ;

TABBRON, HE ;

WINTER, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (11) :2397-2403

[6] REACTIONS OF METAL-TO-METAL MULTIPLE BONDS .1. MU-ALLENE-BIS(CYCLOPENTADIENYL)TETRACARBONYLDIMOLYBDENUM AND BIS(CYCLOPENTADIENYL)DITUNGSTEN COMPOUNDS - PREPARATION, PROPERTIES, AND STRUCTURAL CHARACTERIZATION [J].

BAILEY, WI ;

CHISHOLM, MH ;

COTTON, FA ;

MURILLO, CA ;

RANKEL, LA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (03) :802-807

[7] SIMPLE AND EFFECTIVE PREPARATION OF (ETA-RC5H4)2M2(CO)6 COMPLEXES (M=CR, MO, AND W) [J].

BIRDWHISTELL, R ;

HACKETT, P ;

MANNING, AR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 157 (02) :239-241

[8]

CASEY CP, 1971, CHEM COMMUN, P1220

[9] COMPLEXES OF CYCLIC 2-OXACARBENES .1. SPONTANEOUS CYCLIZATION TO FORM COMPLEX OF 2-OXACYCLOPENTYLIDENE [J].

COTTON, FA ;

LUKEHART, CM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (11) :2672-+

[10]

COTTON FA, 1973, J AM CHEM SOC, V95, P3352

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