A STEREOCONTROLLED METHOD FOR THE SYNTHESIS OF CONJUGATED POLYENES

被引：36

作者：

CROUSSE, B ^{[1
]}

ALAMI, M ^{[1
]}

LINSTRUMELLE, G ^{[1
]}

机构：

[1] ECOLE NORMALE SUPER,CHIM LAB,F-75231 PARIS 05,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 24期

关键词：

1; 2-dichloroethylene; heptaenes; Palladium; pentaenes; polyenes; tetraenes; vinyl chlorides;

D O I：

10.1016/0040-4039(95)00733-S

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient stereocontrolled method for the synthesis of stereodefined conjugated polyenes (e.g.,tetraenes, pentaenes, heptaenes) is described via Pd-catalyzed coupling reaction of terminal alkynes with vinyl chlorides.

引用

页码：4245 / 4248

页数：4

共 19 条

[11] LIU RSH, 1984, TETRAHEDRON, V40, P191
[12] LIPOXINS AND RELATED EICOSANOIDS - BIOSYNTHESIS, BIOLOGICAL PROPERTIES, AND CHEMICAL SYNTHESIS
NICOLAOU, KC
RAMPHAL, JY
PETASIS, NA
SERHAN, CN
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1991, 30 (09) : 1100 - 1116
[13] CHEMISTRY OF AMPHOTERICIN-B - DEGRADATION STUDIES AND PREPARATION OF AMPHOTERONOLIDE-B
NICOLAOU, KC
CHAKRABORTY, TK
OGAWA, Y
DAINES, RA
SIMPKINS, NS
FURST, GT
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (14) : 4660 - 4672
[14] CLATHRYNAMIDE-A, CLATHRYNAMIDE-B, AND CLATHRYNAMIDE-C - NOVEL AMIDES FROM A MARINE SPONGE CLATHRIA SP THAT INHIBIT CELL-DIVISION OF FERTILIZED STARFISH EGGS
OHTA, S
OKADA, H
KOBAYASHI, H
OCLARIT, JM
IKEGAMI, S
[J]. TETRAHEDRON LETTERS, 1993, 34 (37) : 5935 - 5938
[15] STEREOSELECTIVE PREPARATION OF 1-CHLORO-(E,E)-1,3-DIENES - APPLICATION TO THE SYNTHESIS OF METHYL ELEOSTEARATE
RATOVELOMANANA, V
LINSTRUMELLE, G
[J]. TETRAHEDRON LETTERS, 1984, 25 (52) : 6001 - 6004
[16] A CONVENIENT PREPARATION OF TRANS-1-CHLOROALKENES (OR CIS)-1-CHLOROALKENES FROM TRANS-1,2-DICHLOROETHYLENE (OR CIS)-1,2-DICHLOROETHYLENE - A NEW SYNTHESIS OF THE SEX-PHEROMONE OF LOBESIA-BOTRANA
RATOVELOMANANA, V
LINSTRUMELLE, G
[J]. TETRAHEDRON LETTERS, 1981, 22 (04) : 315 - 318
[17] CONVERGENT SYNTHESIS OF THE POLYENE MACROLIDE (-)-ROXATICIN
RYCHNOVSKY, SD
HOYE, RC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (05) : 1753 - 1765
[18] LOW-VALENT TITANIUM REDUCTIVE ELIMINATION - A DIRECT AND HIGHLY STEREOSELECTIVE SYNTHESIS OF VITAMIN-A ALDEHYDE
SOLLADIE, G
BERL, V
[J]. TETRAHEDRON LETTERS, 1992, 33 (24) : 3477 - 3480
[19] OXIDATIVE DOPING OF INTERMEDIATE LENGTH POLYENES - ATTEMPTED OLIGOMERIC MODELING OF DOPED POLYETHYNE
SPANGLER, CW
RATHUNDE, RA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (01) : 26 - 27

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