A STEREOCONTROLLED METHOD FOR THE SYNTHESIS OF CONJUGATED POLYENES

被引：36

作者：

CROUSSE, B ^{[1
]}

ALAMI, M ^{[1
]}

LINSTRUMELLE, G ^{[1
]}

机构：

[1] ECOLE NORMALE SUPER,CHIM LAB,F-75231 PARIS 05,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 24期

关键词：

1; 2-dichloroethylene; heptaenes; Palladium; pentaenes; polyenes; tetraenes; vinyl chlorides;

D O I：

10.1016/0040-4039(95)00733-S

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient stereocontrolled method for the synthesis of stereodefined conjugated polyenes (e.g.,tetraenes, pentaenes, heptaenes) is described via Pd-catalyzed coupling reaction of terminal alkynes with vinyl chlorides.

引用

页码：4245 / 4248

页数：4

共 19 条

[1] CONVENIENT ONE-POT SYNTHESIS OF FUNCTIONALIZED UNSYMMETRICAL (Z)-ENEDIYNES OR (E)-ENEDIYNES FROM (Z)-1,2-DICHLOROETHYLENE OR (E)-1,2-DICHLOROETHYLENE - AN EFFICIENT ROUTE TO (Z,Z,Z) AND (Z,E,Z)-TRIENES
ALAMI, M
CROUSSE, B
LINSTRUMELLE, G
[J]. TETRAHEDRON LETTERS, 1994, 35 (21) : 3543 - 3544
[2] ALAMI M, 1993, SYNLETT, P217
[3] AN EFFICIENT SYNTHESIS OF 1,3(E),5(Z), 1,3(E),5(E) AND 1,3(Z),5(Z)-TRIENES - APPLICATION TO THE SYNTHESIS OF GALBANOLENES AND (9Z,11E)-9,11,13-TETRADECATRIEN-1-YL ACETATE
ALAMI, M
GUEUGNOT, S
DOMINGUES, E
LINSTRUMELLE, G
[J]. TETRAHEDRON, 1995, 51 (04) : 1209 - 1220
[4] THEORETICAL AND EXPERIMENTAL INVESTIGATIONS OF THE NONLINEAR-OPTICAL PROPERTIES OF VANILLIN, POLYENOVANILLIN, AND BISVANILLIN DERIVATIVES
ANDRAUD, C
BROTIN, T
GARCIA, C
PELLE, F
GOLDNER, P
BIGOT, B
COLLET, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (05) : 2094 - 2102
[5] PUSH-PULL POLYENES AND CAROTENOIDS - SYNTHESIS AND NON-LINEAR OPTICAL-PROPERTIES
BLANCHARDDESCE, M
LEDOUX, I
LEHN, JM
MALTHETE, J
ZYSS, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (11) : 737 - 739
[6] STEREOSPECIFIC SYNTHESES AND SPECTROSCOPIC PROPERTIES OF ISOMERIC 2,4,6,8-UNDECATETRAENES - NEW HYDROCARBONS FROM THE MARINE BROWN ALGA-GIFFORDIA-MITCHELLAE .4.
BOLAND, W
SIELER, C
FEIGEL, M
[J]. HELVETICA CHIMICA ACTA, 1987, 70 (04) : 1025 - 1040
[7] PALLADIUM-CATALYZED REACTION OF (E)-DICHLOROETHENE AND (Z)-DICHLOROETHENE WITH 1-ALKYNES - AN EFFICIENT STEREOSPECIFIC SYNTHESIS OF (E)-ENEDIYNES AND (Z)-ENEDIYNES
CHEMIN, D
LINSTRUMELLE, G
[J]. TETRAHEDRON, 1994, 50 (18) : 5335 - 5344
[8] A SHORT STEREOCONTROLLED SYNTHESIS OF LEUKOTRIENE-B4
CHEMIN, D
LINSTRUMELLE, G
[J]. TETRAHEDRON, 1992, 48 (10) : 1943 - 1952
[9] TERMINALLY SUBSTITUTED LINEAR CONJUGATED POLYENES - PRECURSORS OF MOLECULAR WIRES
DUHAMEL, L
DUHAMEL, P
PLE, G
RAMONDENC, Y
[J]. TETRAHEDRON LETTERS, 1993, 34 (46) : 7399 - 7400
[10] THE OSM (OXIDATION-STATE MODIFICATION) CONCEPT - APPLICATION TO A NEW AND RAPID SYNTHESIS OF RETINOIDS
DUHAMEL, L
DUHAMEL, P
ANCEL, JE
[J]. TETRAHEDRON LETTERS, 1994, 35 (08) : 1209 - 1210

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