RUTHENIUM-CATALYZED RING-OPENING METATHESIS POLYMERIZATION OF CYCLOOLEFINS INITIATED BY DIAZOESTERS

被引：107
作者：
DEMONCEAU, A
NOELS, AF
SAIVE, E
HUBERT, AJ
机构：
[1] UNIV LIEGE,MACROMOLEC CHEM & ORGAN CATALYSIS LAB,SART TILMAN B6,B-4000 LIEGE,BELGIUM
[2] UNIV LIEGE,ORGAN SYNTH & CATALYSIS,B-4000 LIEGE,BELGIUM
来源：
JOURNAL OF MOLECULAR CATALYSIS | 1992年 / 76卷 / 1-3期
关键词：
D O I：
10.1016/0304-5102(92)80151-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Addition of catalytic amounts of diazoesters to various ruthenium complexes, including some diruthenium(II,II) tetrakis carboxylates, led to new catalyst systems that promoted the ROMP not only of norbornene (bicyclo[2.2.1]heptene) but also of cyclooctene and cyclopentene. The conversion and the cis content of the polymers varied widely and depended on the nature of the catalyst precursor.
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页码：123 / 132
页数：10
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