HYDROXYLATION OF METHANE BY A STERICALLY HINDERED RUTHENIUM COMPLEX

被引：101

作者：

GOLDSTEIN, AS ^{[1
]}

DRAGO, RS ^{[1
]}

机构：

[1] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 01期

关键词：

D O I：

10.1039/c39910000021

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The sterically crowded cis-[Ru(dmp)2S2](PF6)2 (dmp = 2,9 dimethyl-1,10-phenanthroline, S = Me3CN or H2O) is capable of hydroxylating methane under mild reaction conditions utilizing H2O2 as the primary oxidant; oxidation of this complex with H2O2 is studied spectrophotometrically by UV-VIS and NMR spectroscopy implicating ruthenium(VI) as the active oxidant.

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页码：21 / 22

页数：2

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