UNUSUAL 6-COORDINATED AND 8-COORDINATED CADMIUM(II) MALONATE COMPLEX - RELEVANCE TO CD-113 NMR PROBE OF METAL-BINDING SITES ON METALLOPROTEINS

被引：34
作者：
CHUNG, KH
HONG, E
DO, Y
MOON, CH
机构：
[1] KOREA ADV INST SCI & TECHNOL,DEPT CHEM,YUSUNG KU,TAEJON 305701,SOUTH KOREA
[2] KOREA ADV INST SCI & TECHNOL,CTR MOLEC SCI,YUSUNG KU,TAEJON 305701,SOUTH KOREA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 22期
关键词：
D O I：
10.1039/c39950002333
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Cd-113 NMR spectrum of polymeric tetraaquobis(malonato)dicadmium(II) 1 is characterized by two resonances and its crystal structure shows two cadmium sites in distinct chemical environments; the six- and eight-coordinate sites formed by oxygen donors are correlated with chemical shifts at delta 18 and -107, respectively.
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页码：2333 / 2334
页数：2
相关论文
共 11 条
[1]   CD-113 NUCLEAR MAGNETIC-RESONANCE STUDIES OF METALLOPROTEINS .1. [CD-113]CONCANAVALIN-A - PRELIMINARY INVESTIGATION [J].
BAILEY, DB ;
ELLIS, PD ;
CARDIN, AD ;
BEHNKE, WD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (16) :5236-5237
[2]   CD-113 NUCLEAR MAGNETIC-RESONANCE STUDIES OF CADMIUM-SUBSTITUTED DERIVATIVES OF BOVINE SUPEROXIDE-DISMUTASE [J].
BAILEY, DB ;
ELLIS, PD ;
FEE, JA .
BIOCHEMISTRY, 1980, 19 (03) :591-596
[3]  
BOULANGER Y, 1982, J BIOL CHEM, V257, P13717
[4]   MG2+ BINDING TO PARVALBUMINS STUDIED BY MG-25 AND CD-113 NMR-SPECTROSCOPY [J].
CAVE, A ;
PARELLO, J ;
DRAKENBERG, T ;
THULIN, E ;
LINDMAN, B .
FEBS LETTERS, 1979, 100 (01) :148-152
[5]  
DRAKENBERG T, 1978, FEBS LETT, V92, P346, DOI 10.1016/0014-5793(78)80784-4
[6]   SOLID-STATE AND SOLUTION CD-113 NMR, SHIELDING TENSOR COMPONENTS, AND CRYSTAL AND MOLECULAR-STRUCTURES OF (BIS[2-(3,5-DIMETHYL-1-PYRAZOLYL)ETHYL] OXIDE)BIS(NITRATO-O,O')CADMIUM(II) AND (BIS[2-(3,5-DIMETHYL-1-PYRAZOLYL)ETHYL]AMINE)BIS(NITRATO-O,O')CADMIUM(II) [J].
GRIFFITH, EAH ;
CHARLES, NG ;
LEWINSKI, K ;
AMMA, EL ;
RODESILER, PF .
INORGANIC CHEMISTRY, 1987, 26 (24) :3983-3989
[7]   CD-113 SHIELDING TENSORS OF OXO CADMIUM COMPOUNDS .2. SINGLE-CRYSTAL STUDIES ON CADMIUM CALCIUM TETRAACETATE HEXAHYDRATE, CADMIUM MALEATE DIHYDRATE, CADMIUM FORMATE DIHYDRATE, CADMIUM DIAMMONIUM DISULFATE HEXAHYDRATE, AND CADMIUM DIACETATE DIHYDRATE [J].
HONKONEN, RS ;
ELLIS, PD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (19) :5488-5497
[8]   CD-113 SHIELDING TENSORS OF CADMIUM OXO COMPOUNDS .1. SINGLE-CRYSTAL STUDIES ON CD(NO3)2.4H2O AND 3CDSO4.8H2O [J].
HONKONEN, RS ;
DOTY, FD ;
ELLIS, PD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (13) :4163-4168
[9]   CD-113 NMR-STUDIES OF SOLID CADMIUM(II) COMPLEXES [J].
MENNITT, PG ;
SHATLOCK, MP ;
BARTUSKA, VJ ;
MACIEL, GE .
JOURNAL OF PHYSICAL CHEMISTRY, 1981, 85 (14) :2087-2091
[10]   CRYSTAL-STRUCTURE OF POLYMERIC CADMIUM(II) MALONATE MONOHYDRATE [J].
POST, ML ;
TROTTER, J .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (17) :1922-1925
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