3,3-DIMETHYLALLYLDIISOPINOCAMPHEYLBORANE - A NOVEL REAGENT FOR CHIRAL ISOPRENYLATION OF ALDEHYDES - SYNTHESIS OF (+)-ARTEMISIA AND (-)-ARTEMISIA ALCOHOL IN EXCEPTIONALLY HIGH ENANTIOMERIC PURITY

被引：61

作者：

BROWN, HC

JADHAV, PK

机构：

来源：

TETRAHEDRON LETTERS | 1984年 / 25卷 / 12期

关键词：

D O I：

10.1016/S0040-4039(01)80116-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：1215 / 1218

页数：4

共 18 条

[1]

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[3] ASYMMETRIC REDUCTION OF PROCHIRAL ALPHA-HALO KETONES WITH B-3-PINANYL-9-BORABICYCLO[3.3.1]NONANE [J].

BROWN, HC ;

PAI, GG .

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[4] HYDROBORATION .61. DIISOPINOCAMPHEYLBORANE OF HIGH OPTICAL PURITY - IMPROVED PREPARATION AND ASYMMETRIC HYDROBORATION OF REPRESENTATIVE CIS-DISUBSTITUTED ALKENES [J].

BROWN, HC ;

DESAI, MC ;

JADHAV, PK .

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[5] ASYMMETRIC CARBON CARBON BOND FORMATION VIA BETA-ALLYLDIISOPINOCAMPHEYLBORANE - SIMPLE SYNTHESIS OF SECONDARY HOMOALLYLIC ALCOHOLS WITH EXCELLENT ENANTIOMERIC PURITIES [J].

BROWN, HC ;

JADHAV, PK .

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[6]

BROWN HC, UNPUB

[7]

COREY EJ, 1975, TETRAHEDRON LETT, P2647

[8] SURVEY OF SOME IRREGULAR MONOTERPENES AND THEIR BIOGENETIC ANALOGIES TO PRESQUALENE ALCOHOL [J].

EPSTEIN, WW ;

POULTER, CD .

PHYTOCHEMISTRY, 1973, 12 (04) :737-747

[9]

GRANDI R, 1976, PHYTOCHEMISTRY, V15, P1771

[10] ORGANOBORANES .20. FACILE ALLYLBORATION OF REPRESENTATIVE CARBONYL-COMPOUNDS WITH B-ALLYL DERIVATIVES OF 9-BORABICYCLO[3.3.1]NONANE [J].

KRAMER, GW ;

BROWN, HC .

JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (13) :2292-2299

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