PREPARATION, CHARACTERIZATION AND CATALYTIC PROPERTIES OF COBALT PHTHALOCYANINE ENCAPSULATED IN ZEOLITE EMT

被引：0
|
作者：
ERNST, S
TRAA, Y
DEEG, U
机构：
来源：
ZEOLITES AND RELATED MICROPOROUS MATERIALS: STATE OF THE ART 1994 | 1994年 / 84卷
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The synthesis of cobalt phthalocyanine (CoPc) in the large cages of zeolite EMT via the ship-in-the-bottle strategy is described. A detailed physicochemical characterization together with mass balances reveals that loadings of up to one CoPc complex in every sixth supercage can be achieved. CoPc encaged in zeolite EMT is an active catalyst for the oxidation of ethylbenzene with molecular oxygen. Maximum turnover numbers (defined as n(E-Bz, converted)/n(CoPc, encaged)) of ca. 22 000 are observed.
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页码：925 / 932
页数：8
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