OXIDATION REACTIONS USING UREA HYDROGEN-PEROXIDE - A SAFE ALTERNATIVE TO ANHYDROUS HYDROGEN-PEROXIDE

被引：221

作者：

COOPER, MS ^{[1
]}

HEANEY, H ^{[1
]}

NEWBOLD, AJ ^{[1
]}

SANDERSON, WR ^{[1
]}

机构：

[1] LAPORTE RES & DEV,INTEROX RES & DEV,WIDNES,CHESHIRE,ENGLAND

来源：

SYNLETT | 1990年 / 09期

关键词：

D O I：

10.1055/s-1990-21156

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Urea-hydrogen peroxide (UHP) alone or in combination with carboxylic anhydrides has been shown to serve as a valuable alternative to anhydrous hydrogen peroxide: the range of substrates oxidised include alkenes (epoxidation), ketones (Baeyer-Villiger reaction), sulphides (to sulphones), nitrogen heterocycles (to N-oxides), and aromatic hydrocarbons (to phenols). © 1990 Georg Thieme Verlag. All rights reserved.

引用

页码：533 / 535

页数：3

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