CATALYSIS BY ZWITTERIONIC MICELLES IN AROMATIC NUCLEOPHILIC-SUBSTITUTION REACTION

被引：10
|
作者：
CIPICIANI, A
PRIMIERI, S
机构：
[1] Dipartimento di Chimica, Università di Perugia, Perugia, 06100
来源：
TETRAHEDRON | 1991年 / 47卷 / 01期
关键词：
D O I：
10.1016/0040-4020(91)80010-Y
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The kinetics of the reaction of OH- with 1-chloro-2,4-dinitronaphthalene (1) in the presence of N,N-dimethyl-N-tetradecylglycine (DTG) and N,N-dimethyl-N-hexadecylglycine (DHG) were studied. kobs against [surfactant] increases sharply at low [surfactant] and then tends to level off either at low [OH-] added or at high [OH-] added. Rate effects were compared with those obtained in the presence of normal cationic micelles. © 1991.
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页码：83 / 90
页数：8
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