OXYGENATION UNDER UV-LIGHT OF ALLYLSILANES CATALYZED BY PALLADIUM(II) AND OF (ETA(3)-ALLYL)PALLADIUM COMPLEXES - A MECHANISTIC APPROACH

被引：12

作者：

MUZART, J

RIAHI, A

机构：

[1] Units de Recherche “Réarrangements Thermiques, Photochimiques”, CNRS, UFR Sciences, Université de Champagne-Ardenne

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 10期

关键词：

D O I：

10.1021/om00046a061

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of 1-phenyl-3-(trimethylsilyl)-1-propene, 1-phenyl-1-(trimethylsilyl)-2-propene, and bi(mu-chloro)bis(1,2,3-eta3)-1-phenylpropenyl)dipalladium as substrates led us to reject a free-radical mechanism for the title reactions and to retain an incorporation of oxygen at the level of a common organopalladium intermediate.

引用

页码：3478 / 3481

页数：4

共 41 条

[21] STRUCTURE AND CHEMISTRY OF PI-ALLYL PALLADIUM COMPLEXES FROM STEROIDS [J].

MAHE, C ;

PATIN, H ;

VANHULLE, MT ;

BARTON, DHR .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1981, (09) :2504-2508

[22] REGIOSELECTIVE PHOTO-OXIDATION OF ETA-3-ALLYLPALLADIUM - ACCESS TO GAMMA-FUNCTIONALIZED ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS [J].

MUZART, J ;

PALE, P ;

PETE, JP .

TETRAHEDRON LETTERS, 1983, 24 (42) :4567-4568

[23] PALLADIUM-CATALYZED ALLYLIC OXIDATION OF 1-(PARA-TOLUENESULFONYL)-2-PROPENE AND 1-(TRIMETHYLSILYL)-1-(PARA-TOLUENESULFONYL)-2-PROPENE [J].

MUZART, J ;

PETE, JP ;

RIAHI, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 331 (01) :113-119

[24] REGIOSELECTIVE OXIDATION OF ALLYL SULFONES CATALYZED BY PALLADIUM AND LIGHT - FORMATION OF ALDEHYDES AND BETA-SULFONYL ALPHA,BETA-ETHYLENIC ALCOHOLS [J].

MUZART, J ;

RIAHI, A ;

PETE, JP .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 280 (02) :269-279

[25]

MUZART J, 1988, B SOC CHIM FR, P731

[26] PREPARATION OF 1,5-DIENES BY PHOTOLYSIS OF ETA-3-ALLYLPALLADIUM COMPLEXES [J].

MUZART, J ;

PETE, JP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (06) :257-258

[27] PALLADIUM-ULTRAVIOLET-LIGHT-CATALYZED MOLECULAR-OXYGEN ALKENE-OXIDATION [J].

MUZART, J ;

PALE, P ;

PETE, JP .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 353 (02) :267-273

[28] PHOTO-ACTIVATION OF ALKENE OXIDATION BY MOLECULAR-OXYGEN IN THE PRESENCE OF PALLADIUM [J].

MUZART, J ;

PALE, P ;

PETE, JP .

TETRAHEDRON LETTERS, 1982, 23 (35) :3577-3578

[29] PREPARATION OF CONJUGATED CARBONYL-COMPOUNDS BY PHOTOLYSIS OF ETA-3-ALLYLPALLADIUM COMPLEXES [J].

MUZART, J ;

PALE, P ;

PETE, JP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (14) :668-669

[30]

MUZART J, 1984, B SOC CHIM FR 2, V56

← 1 2 3 4 5 →