OXYGENATION UNDER UV-LIGHT OF ALLYLSILANES CATALYZED BY PALLADIUM(II) AND OF (ETA(3)-ALLYL)PALLADIUM COMPLEXES - A MECHANISTIC APPROACH

被引：12

作者：

MUZART, J

RIAHI, A

机构：

[1] Units de Recherche “Réarrangements Thermiques, Photochimiques”, CNRS, UFR Sciences, Université de Champagne-Ardenne

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 10期

关键词：

D O I：

10.1021/om00046a061

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of 1-phenyl-3-(trimethylsilyl)-1-propene, 1-phenyl-1-(trimethylsilyl)-2-propene, and bi(mu-chloro)bis(1,2,3-eta3)-1-phenylpropenyl)dipalladium as substrates led us to reject a free-radical mechanism for the title reactions and to retain an incorporation of oxygen at the level of a common organopalladium intermediate.

引用

页码：3478 / 3481

页数：4

共 41 条

[1]

AKHREM IS, 1983, RUSS CHEM REV, V52, P542

[2] DIOXYGEN INSERTION INTO IRON(III)-CARBON BONDS - NMR-STUDIES OF THE FORMATION AND REACTIVITY OF ALKYLPEROXO COMPLEXES OF IRON(III) PORPHYRINS [J].

ARASASINGHAM, RD ;

BALCH, AL ;

CORNMAN, CR ;

LATOSGRAZYNSKI, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (12) :4357-4363

[3] ALLYLIC OXIDATIONS BY PEROXY ESTERS CATALYZED BY COPPER-SALTS - THE POTENTIAL FOR STEREOSELECTIVE SYNTHESES [J].

BECKWITH, ALJ ;

ZAVITSAS, AA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (26) :8230-8234

[4]

BRAUN AM, 1986, TECHNOLOGIE PHOTOCHI, pCH11

[5] ORGANOIRON-MEDIATED OXYGENATION OF ALLYLIC ORGANOTIN COMPOUNDS - A POSSIBLE CHEMICAL-MODEL FOR ENZYMATIC LIPOXYGENATION [J].

COREY, EJ ;

WALKER, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (26) :8108-8109

[6]

CORRIU RJP, 1984, J ORGANOMET CHEM, V277, pC7

[7] PHOTOLYSIS OF ETA-3-ALLYLPALLADIUM COMPLEXES - STUDY BY ELECTRONIC PARAMAGNETIC-RESONANCE OF ALLYLIC NITROXIDES FORMED IN THE PRESENCE OF NITROSODURENE [J].

CROZET, MP ;

MUZART, J ;

PALE, P ;

TORDO, P .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 244 (02) :191-200

[8] ENE REACTIONS OF ALLYLIC TIN-COMPOUNDS WITH SINGLET OXYGEN [J].

DANG, HS ;

DAVIES, AG .

TETRAHEDRON LETTERS, 1991, 32 (14) :1745-1748

[9] PHOTOREACTIVITY OF (ETA-3-ALLYL)PALLADIUM COMPLEXES IN THE PRESENCE OF ORGANIC HALIDES [J].

DEPOORTER, B ;

MUZART, J ;

PETE, JP .

ORGANOMETALLICS, 1983, 2 (11) :1494-1497

[10]

Fleming I., 1989, ORG REACTIONS, V37, P57

← 1 2 3 4 5 →