SYNTHESIS OF TORRENTIN, DIHYDROSANTAMARINE, AND SAUSSUREA LACTONE FROM SANTONIN

被引：7

作者：

BLAY, G ^{[1
]}

CARDONA, L ^{[1
]}

GARCIA, B ^{[1
]}

PEDRO, JR ^{[1
]}

机构：

[1] UNIV VALENCIA,FAC CHEM,DEPT ORGAN CHEM,E-46100 VALENCIA,SPAIN

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1992年 / 70卷 / 03期

关键词：

EUDESMANOLIDE; ELEMANOLIDE; SANTONIN; TORRENTIN; SAUSSUREA LACTONE;

D O I：

10.1139/v92-107

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of the eudesmanolide torrentin (1) by sensitized photooxygenation of synthetic dihydrosantamarine (3) is reported. Both dihydrosantamarine and dihydroreynosin (11) were obtained from the 1,2-epoxide 9, which, in turn, was prepared from the diselenide 7. An improved procedure for the synthesis of the elemanolide saussurea lactone (4) is also reported.

引用

页码：817 / 822

页数：6

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