STRUCTURE AND PROPERTIES OF POLY(3-HYDROXYBUTYRATE-CO-4-HYDROXYBUTYRATE) PRODUCED BY ALCALIGENES LATUS

被引：35
|
作者：
KANG, CK [1 ]
KUSAKA, S [1 ]
DOI, Y [1 ]
机构：
[1] AKEBONO R&D CTR,HANYUU,SAITAMA 348,JAPAN
来源：
BIOTECHNOLOGY LETTERS | 1995年 / 17卷 / 06期
关键词：
D O I：
10.1007/BF00129382
中图分类号：
Q81 [生物工程学（生物技术）]; Q93 [微生物学];
学科分类号：
071005 ; 0836 ; 090102 ; 100705 ;
摘要：
Random copolymers of 3-hydroxybutyrate (3HB) and 4-hydroxybutyrate (4HB) with a wide range of compositions varying from 0 to 83 mol% 4HB were produced by Alcaligenes latus from the mixed carbon substrates of 3-hydroxybutyric and 4-hydroxybutyric acids. The structure and physical properties of P(3HB-co-4HB) were characterized by H-1 and C-13 NMR spectroscopy, gel-permeation chromatography, and differential scanning calorimetry. The isothermal radial growth rates of spherulites of P(3HB-co-4HB) were much slower than the rate of P(3HB) homopolymer. The enzymatic degradation rates of P(3HB-co-4HB) films by a PHB depolymerase were strongly influenced by the copolymer composition.
引用
收藏
页码：583 / 588
页数：6
相关论文
共 50 条
  • [31] Effect of chain extension on processability and mechanical properties of poly(3-hydroxybutyrate-co-4-hydroxybutyrate)
    Yang, Zhitao
    Li, Cheng
    Liu, Yong
    Zhang, Zhen
    Cao, Xianwu
    JOURNAL OF APPLIED POLYMER SCIENCE, 2024, 141 (24)
  • [32] MICROBIAL SYNTHESIS AND PROPERTIES OF POLY(3-HYDROXYBUTYRATE-CO-4-HYDROXYBUTYRATE) IN COMAMONAS-ACIDOVORANS
    SAITO, Y
    DOI, Y
    INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 1994, 16 (02) : 99 - 104
  • [33] Morphology and properties of biodegradable and biosourced polylactide blends with poly(3-hydroxybutyrate-co-4-hydroxybutyrate)
    Han, Lijing
    Han, Changyu
    Zhang, Huiliang
    Chen, Shan
    Dong, Lisong
    POLYMER COMPOSITES, 2012, 33 (06) : 850 - 859
  • [34] Poly(3-hydroxybutyrate-co-4-hydroxybutyrate) formation from γ-aminobutyrate and glutamate
    Valentin, HE
    Reiser, S
    Gruys, KJ
    BIOTECHNOLOGY AND BIOENGINEERING, 2000, 67 (03) : 291 - 299
  • [35] PRODUCTION OF POLY(3-HYDROXYBUTYRATE-CO-4-HYDROXYBUTYRATE) BY PSEUDOMONAS-ACIDOVORANS
    KIMURA, H
    YOSHIDA, Y
    DOI, Y
    BIOTECHNOLOGY LETTERS, 1992, 14 (06) : 445 - 450
  • [36] Crystallization behaviors and morphology of biodegradable poly(3-hydroxybutyrate-co-4-hydroxybutyrate)
    Wen, Xing
    Lu, Xiuping
    Peng, Quan
    Zhu, Fuyan
    Zheng, Ning
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2012, 109 (02) : 959 - 966
  • [37] Production of Hydroxybutyrate Monomers by Pseudomonas mendocina Biodegraded Poly (3-hydroxybutyrate-co-4-hydroxybutyrate)
    Mao, Hailong
    Li, Linlin
    Jiang, Husheng
    Wang, Zhanyong
    JOURNAL OF PURE AND APPLIED MICROBIOLOGY, 2014, 8 (03): : 1875 - 1882
  • [38] Supercritical CO2 Foaming of Poly(3-hydroxybutyrate-co-4-hydroxybutyrate)
    Zhang, Tao
    Jang, Yunjae
    Lee, Eunhye
    Shin, Sooan
    Kang, Ho-Jong
    POLYMERS, 2022, 14 (10)
  • [39] Thermal degradation behavior of poly[(R)-3-hydroxybutyrate-co-4-hydroxybutyrate]
    Omura, Taku
    Goto, Tatsuya
    Maehara, Akira
    Kimura, Satoshi
    Abe, Hideki
    Iwata, Tadahisa
    POLYMER DEGRADATION AND STABILITY, 2021, 183
  • [40] Tailoring the surface architecture of poly(3-hydroxybutyrate-co-4-hydroxybutyrate) scaffolds
    Vigneswari, S.
    Majid, M. I. A.
    Amirul, A. A.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 124 (04) : 2777 - 2788
12345