SYNTHESIS OF ALPHA,BETA-UNSATURATED (S)-CYANOHYDRINS USING THE OXYNITRILASE FROM HEVEA-BRASILIENSIS

被引:55
作者
KLEMPIER, N [1 ]
PICHLER, U [1 ]
GRIENGL, H [1 ]
机构
[1] GRAZ TECH UNIV,INST ORGAN CHEM & SPEZIALFORSCH BEREICH BIOKATALY,A-8010 GRAZ,AUSTRIA
关键词
D O I
10.1016/0957-4166(95)00085-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
alpha,beta-unsaturated (S)-cyanohydrins derived from 2-propenal, 2-butenal, (E) and (Z)-2-hexenal and 2-hexynal are obtained in high enantiomeric purity (80-95% e.e.) by using an oxynitrilase isolated from the leaves of Hevea brasiliensis.
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页码:845 / 848
页数:4
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