ELECTROCHEMICAL GENERATION OF REACTIVE NITROGEN SPECIES .14. ANODIC-OXIDATION OF N-ACYL-N',N'-DIMETHYLHYDRAZINES

被引：2

作者：

FUCHIGAMI, T

SATO, T

NONAKA, T

机构：

[1] Department of Electronic Chemistry, Tokyo Institute of Technology, Midori-Ku, Yokohama, 227

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 291卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(90)87182-J

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The anodic behavior of N-acyl-N', N'-dimethylhydrazines was studied. Cyclic voltammograms of these hydrazines showed two anodic peaks and the second peak corresponded to the oxidation of the corresponding N, N,-coupling products. Macro-scale electrolysis at the first peak potential provided the N,N-coupling products, tetrazanes in reasonable yields. © 1990.

引用

收藏

页码：141 / 145

页数：5

相关论文

共 16 条

[1] ELECTROCHEMICAL OXIDATION OF PRIMARY ALIPHATIC AMINES [J].

BARNES, KK ;

MANN, CK .

JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (05) :1474-&

[2]

Bauer R., 1978, ANGEW CHEM, V90, P214

[3] ELECTROCHEMICAL OXIDATION OF TERT-BUTYLAMINE TO 2,2'-AZOISOBUTANE [J].

BLACKHAM, AU ;

KWAK, S ;

PALMER, JL .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1975, 122 (08) :1081-1082

[4]

CAUQUIS G, 1972, J ELECTROANAL CHEM, V40, P6

[5] ELECTROCHEMICAL GENERATION OF UNSTABLE NITROGEN SPECIES .3. ELECTROCHEMICAL OXIDATION OF 3,3,7,7-TETRAETHYL-PERHYDRO-1,5-DIAZOCINE [J].

FUCHIGAMI, T ;

IWAOKA, T ;

NONAKA, T ;

SEKINE, T .

CHEMISTRY LETTERS, 1978, (12) :1437-1440

[6] ELECTROCHEMICAL GENERATION OF REACTIVE NITROGEN SPECIES .13. ANODIC-OXIDATION OF ANILINES HAVING ELECTRON-WITHDRAWING GROUPS AT THEIR ALPHA-POSITIONS [J].

FUCHIGAMI, T ;

FUJITA, Y ;

NONAKA, T .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 284 (01) :115-126

[7]

FUCHIGAMI T, 1979, J ELECTROCHEM SOC JP, V47, P627

[8]

FUCHIGAMI T, 1979, B CHEM SOC JPN, V53, P2040

[9]

FUCHIGAMI T, 1984, J CHEM SOC JPN, P1769

[10] THE SYNTHESIS OF ALKYLHYDRAZINES .1. THE REACTION OF LITHIUM ALUMINUM HYDRIDE WITH MONOACYLHYDRAZINES AND DIACYLHYDRAZINES [J].

HINMAN, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (08) :1645-1649