TUNING THE ELECTRONIC-PROPERTIES OF PHENANTHROLINE LIGANDS - 3,8-BIS(ARYLETHYNYL)-1,10-PHENANTHROLINES AND THEIR RU(II) COMPLEXES

被引：49

作者：

TZALIS, D ^{[1
]}

TOR, Y ^{[1
]}

机构：

[1] UNIV CALIF SAN DIEGO,DEPT CHEM & BIOCHEM,LA JOLLA,CA 92093

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 34期

关键词：

D O I：

10.1016/0040-4039(95)01190-S

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed cross-coupling reactions between 3,8-dibromo-1,10-phenanthroline and substituted phenylacetylenes provide a navel family of highly conjugated metal chelators. The electronic transitions of the ligands and their Ru(II) complexes are affected by the nature of the substituents on the conjugated phenyl rings.

引用

页码：6017 / 6020

页数：4

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