DINUCLEAR 5-CO-ORDINATE ZINC-COMPLEXES BRIDGED BY A PHOSPHATE MONOESTER OR AN INORGANIC-PHOSPHATE GROUP

被引：34

作者：

ADAMS, H ^{[1
]}

BAILEY, NA ^{[1
]}

FENTON, DE ^{[1
]}

HE, QY ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,DAINTON BLDG,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 04期

关键词：

D O I：

10.1039/dt9950000697

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two dinuclear five-co-ordinated zinc complexes, derived from tris[(2-pyridyl)methyl]amine and bridged by a phosphate monoester or an inorganic phosphate group respectively, have been synthesized; the structure of the former has been established by X-ray crystallography and shows the bridging mode of the phosphate to be syn-anti whereas in alkaline phosphatase it is syn-syn.

引用

页码：697 / 699

页数：3

共 22 条

[1] PYRIDINE DERIVATIVES AS COMPLEX FORMERS .8. PRODUCTION OF A NEW 4 AND A NEW 6 TOOTH LIGAND [J].

ANDEREGG, G ;

WENK, F .

HELVETICA CHIMICA ACTA, 1967, 50 (08) :2330-&

[2] PYRIDINE-DERIVATIVES AS COMPLEXING AGENTS .11. THERMODYNAMICS OF METAL-COMPLEX FORMATION WITH BIS[(2-PYRIDYL)METHYL]-AMINE, TRIS[(2-PYRIDYL)METHYL]-AMINE AND TETRAKIS[(2-PYRIDYL)METHYL]-AMINE [J].

ANDEREGG, G ;

HUBMANN, E ;

PODDER, NG ;

WENK, F .

HELVETICA CHIMICA ACTA, 1977, 60 (01) :123-140

[3] MONONUCLEAR AND DINUCLEAR ZINC(II) COMPLEXES OF BIOLOGICAL RELEVANCE - CRYSTAL-STRUCTURES OF [L2ZN](PF6)2, [L'ZN(O2CPH)2(H2O)], [L'2ZN2(MU-OH)2](CLO4)2, AND [L'2ZN2(MU-OH)(MU-CH3CO2)2](CLO4)BULLET-H2O (L = 1,4,7-TRIAZACYCLONONANE, L' = 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE) [J].

CHAUDHURI, P ;

STOCKHEIM, C ;

WIEGHARDT, K ;

DECK, W ;

GREGORZIK, R ;

VAHRENKAMP, H ;

NUBER, B ;

WEISS, J .

INORGANIC CHEMISTRY, 1992, 31 (08) :1451-1457

[4] MONONUCLEAR AND DINUCLEAR M-2+ CHELATES AS CATALYSTS FOR THE HYDROLYSIS OF ORGANO-PHOSPHATE TRIESTERS [J].

CLEWLEY, RG ;

SLEBOCKATILK, H ;

BROWN, RS .

INORGANICA CHIMICA ACTA, 1989, 157 (02) :233-238

[5] MODEL COMPOUNDS FOR THE OXIDIZED UTEROFERRIN PHOSPHATE COMPLEX - SYNTHESES, CRYSTAL-STRUCTURES, AND MAGNETIC-PROPERTIES OF MU-PHOSPHATO-BRIDGED, MU-ARSENATO-BRIDGED, AND MU-CHROMATO-BRIDGED BINUCLEAR IRON(III) COMPLEXES [J].

DRUEKE, S ;

WIEGHARDT, K ;

NUBER, B ;

WEISS, J ;

FLEISCHHAUER, HP ;

GEHRING, S ;

HAASE, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (23) :8622-8631

[6] THE EMERGENCE OF TRINUCLEAR CONSTELLATIONS AT METALLOBIOSITES [J].

FENTON, DE ;

OKAWA, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (09) :1349-1357

[7] PHOSPHATE ESTER CLEAVAGE WITH A ZINC HYDROXIDE COMPLEX - FORMATION AND CRYSTAL-STRUCTURE OF A DINUCLEAR ZINC COMPLEX BRIDGED WITH A PHOSPHATE MONOESTER [J].

HIKICHI, S ;

TANAKA, M ;

MOROOKA, Y ;

KITAJIMA, N .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (11) :814-815

[8] STRUCTURE AND SYNTHESIS OF ISOMERS OF NOVEL BINUCLEAR COBALT(III) PHENYL PHOSPHATE COMPLEXES [J].

JONES, DR ;

LINDOY, LF ;

SARGESON, AM ;

SNOW, MR .

INORGANIC CHEMISTRY, 1982, 21 (12) :4155-4160

[9] REACTION-MECHANISM OF ALKALINE-PHOSPHATASE BASED ON CRYSTAL-STRUCTURES - 2-METAL ION CATALYSIS [J].

KIM, EE ;

WYCKOFF, HW .

JOURNAL OF MOLECULAR BIOLOGY, 1991, 218 (02) :449-464

[10] MACROCYCLIC POLYAMINE ZINC(II) COMPLEXES AS ADVANCED MODELS FOR ZINC(II) ENZYMES [J].

KIMURA, E .

PROGRESS IN INORGANIC CHEMISTRY, VOL 41, 1994, 41 :443-491

← 1 2 3 →