SUPRAMOLECULAR ORIENTATION OF CONJUGATED PORPHYRIN OLIGOMERS IN STRETCHED POLYMERS

被引：25

作者：

ANDERSON, HL ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

ADVANCED MATERIALS | 1994年 / 6卷 / 11期

关键词：

D O I：

10.1002/adma.19940061104

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Communication: Conjugated porphyrin oligomers show strong optical dichroism when oriented in a stretched polymer matrix. It is shown that the zinc porphyrin polymer (approximately 10 repeat units) aligns, as expected, with its backbone in the stretch direction, whereas the dimer orients with its molecular plane perpendicular to the stretch. This anomalous behavior is explained as being due to the formation of supramolecular stacks that orient as single units.

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页码：834 / 836

页数：3

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