CO2 REDUCTION TO CH4 WITH H-2 ON PHOTOIRRADIATED TS-1

被引：30

作者：

YAMAGATA, S

NISHIJO, M

MURAO, N

OHTA, S

MIZOGUCHI, I

机构：

[1] Department of Sanitary Engineering, Faculty of Engineering, Hokkaido University, Sapporo

来源：

ZEOLITES | 1995年 / 15卷 / 06期

关键词：

TITANIUM SILICALITE; TS-1; TIO2; CO2; PHOTOCATALYSIS; CH4;

D O I：

10.1016/0144-2449(95)00020-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

CO, reduction on reduced titanium silicalite (TS-1) with photoirradiation in the presence of H-2 was investigated in a closed circulation system, CO2 was reduced to give CH4 under u.v. irradiation, which TS-1 absorbs. The amount of the carbon species on TS-1 after photoirradiation indicated that all Ti atoms in the framework may act as a photocatalytic site. Infrared spectrum of TS-1 after the reaction showed that - CH2 - and -CH3 were left on TS-1.

引用

页码：490 / 493

页数：4

共 48 条

[1] PHOTOCATALYTIC REDUCTION OF CO-2 ON ANCHORED TITANIUM-OXIDE CATALYSTS [J].