SYNTHESIS, CHARACTERIZATION, AND PROPERTIES OF A SERIES OF OSMIUM-CONTAINING AND RUTHENIUM-CONTAINING METALLOPOLYMERS

被引：227
作者：
FORSTER, RJ [1 ]
VOS, JG [1 ]
机构：
[1] DUBLIN CITY UNIV,SCH CHEM SCI,DUBLIN 9,IRELAND
来源：
MACROMOLECULES | 1990年 / 23卷 / 20期
关键词：
D O I：
10.1021/ma00222a008
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A series of metallopolymers, based on poly(4-vinylpyridine) (PVP) and poly(N-vinylimidazole) (PVI), has been prepared containing both osmium and ruthenium bis(2,2’-bipyridyl) centers. The polymers have been characterized by using UV-vis and emission spectroscopies. The results obtained are compared with those obtained for the metallopolymers containing only osmium or ruthenium centers as well as model monomeric complexes. Some electrochemical and photochemical properties of glassy carbon electrodes modified with these materials are also reported. © 1990, American Chemical Society. All rights reserved.
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页码：4372 / 4377
页数：6
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