A NEW LIGAND FOR THE SELF ASSEMBLY OF STARBURST COORDINATION OLIGOMERS AND POLYMERS

被引：60

作者：

CONSTABLE, EC

THOMPSON, AMWC

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 08期

关键词：

D O I：

10.1039/c39920000617

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination properties of the tridentate ligand 2,2' : 6',2"-terpyridine (tpy) make it an ideal structural unit to control the assembly of coordination oligomers and polymers, and the new ligand 1,3,5-tris[4'-(2,2' : 6',2"-terpyridinyl)]benzene (ttpy) has been prepared as a building block for the assembly of coordination polymers, the complex [{(tpy)Ru}3(ttpy)][PF6]6 having been prepared; in the trinuclear complex, the three ruthenium(II) centres are equivalent and oxidise at the same potential.

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页码：617 / 619

页数：3

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