THE INTERACTION OF FORMIC-ACID WITH TRANSITION-METAL SURFACES, STUDIED IN ULTRAHIGH-VACUUM

被引：110
作者：
COLUMBIA, MR
THIEL, PA
机构：
[1] IOWA STATE UNIV SCI & TECHNOL, DEPT CHEM, AMES, IA 50011 USA
[2] IOWA STATE UNIV SCI & TECHNOL, AMES LAB, AMES, IA 50011 USA
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1994年 / 369卷 / 1-2期
关键词：
D O I：
10.1016/0022-0728(94)87077-2
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
In this report, we review the interaction of formic acid (HCOOH) with transition metal surfaces, as studied with the tools of modern surface science in an ultrahigh vacuum environment. Our goal is to provide a broad overview of the fundamental adsorption and decomposition processes which HCOOH undergoes at the surfaces of these metals. The metal substrates include Cu, Fe, W, Ni, Ru, Ag, Pt, Au, Rh and Pd.
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页码：1 / 14
页数：14
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[1]   SURFACE-REACTION MODIFICATION - THE EFFECT OF STRUCTURED OVERLAYERS OF SULFUR ON THE KINETICS AND MECHANISM OF THE DECOMPOSITION OF FORMIC-ACID ON PT(111) [J].
ABBAS, N ;
MADIX, RJ .
APPLICATIONS OF SURFACE SCIENCE, 1983, 16 (3-4) :424-440
[2]  
AVERY NR, 1982, SURF SCI, V122, pL574
[3]   ADSORPTION OF FORMIC-ACID ON CLEAN AND OXYGEN COVERED PT(111) [J].
AVERY, NR .
APPLICATIONS OF SURFACE SCIENCE, 1982, 11-2 (JUL) :774-783
[4]   ACID-BASE REACTIONS ON SOLID-SURFACES - THE REACTIONS OF HCOOH, H2CO, AND HCOOCH3 WITH OXYGEN ON AG(110) [J].
BARTEAU, MA ;
BOWKER, M ;
MADIX, RJ .
SURFACE SCIENCE, 1980, 94 (2-3) :303-322
[5]   DECOMPOSITION OF FORMIC-ACID ON NI (100) [J].
BENZIGER, JB ;
MADIX, RJ .
SURFACE SCIENCE, 1979, 79 (02) :394-412
[6]   REACTIONS AND REACTION INTERMEDIATES ON IRON SURFACES .2. HYDROCARBONS AND CARBOXYLIC-ACIDS [J].
BENZIGER, JB ;
MADIX, RJ .
JOURNAL OF CATALYSIS, 1980, 65 (01) :49-58
[7]   DECOMPOSITION OF FORMIC-ACID ON W(100) AND W(100)-(5X1) C-SURFACES [J].
BENZIGER, JB ;
KO, EI ;
MADIX, RJ .
JOURNAL OF CATALYSIS, 1979, 58 (01) :149-153
[8]   REACTIONS AND REACTION INTERMEDIATES ON IRON SURFACES .4. THERMODYNAMICS OF SURFACE-REACTIONS [J].
BENZIGER, JB ;
MADIX, RJ .
JOURNAL OF CATALYSIS, 1982, 74 (01) :67-76
[9]   INFLUENCE OF ADSORBATE INTERACTIONS ON HETEROGENEOUS REACTION-KINETICS - FORMIC-ACID DECOMPOSITION ON NICKEL [J].
BENZIGER, JB ;
SCHOOFS, GR .
JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (19) :4439-4444
[10]   ULTRAVIOLET PHOTOELECTRON SPECTROSCOPIC STUDY OF THE CHEMISORPTION AND DECOMPOSITION OF FORMIC-ACID ON W(100) [J].
BHATTACHARYA, AK .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1979, 75 :863-871
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