GEOCHEMISTRY AND ORIGIN OF A BLACK MUDSTONE IN A VOLCANICLASTIC ENVIRONMENT, ORDOVICIAN LOWER RHYOLITIC TUFF FORMATION, NORTH WALES, UK

Black mudstones in marine volcaniclastic environments have been interpreted both as non-volcanic 'background' sedimentation and as fine grained vitric dust from the waning stages of primary volcanism. Although difficult to distinguish by standard petrographic techniques, differentiation between the two is crucial when attempting to determine sedimentation rates or to infer periods of volcanic quiescence. In the Ordovician Lower Rhyolitic Tuff Formation of North Wales such a fine grained black unit at Cwm Idwal is geochemically similar to an underlying rhyolite ash flow tuff. Its chemical index of alteration (CIA) is identical to that of the tuff. These data suggest that the black mudstone unit is a vitric tuff related to the underlying ash flow tuff. Use of a CIA in addition to trace element geochemistry should, in most cases, serve to distinguish tuffs from silicified mudstones.