THE 1ST STABLE ALDEHYDE AND KETONE COMPLEXES OF ZINC - THE STRUCTURE OF [ZN(SEC6H2BUT3)2(PARA-O=CHC6H4OME)]2

被引：38

作者：

BOCHMANN, M ^{[1
]}

WEBB, KJ ^{[1
]}

HURSTHOUSE, MB ^{[1
]}

MAZID, M ^{[1
]}

机构：

[1] QUEEN MARY & WESTFIELD COLL,DEPT CHEM,LONDON E1 4NS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 24期

关键词：

D O I：

10.1039/c39910001735

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Zn(EC6H2But3)2 (E = S or Se) with organic carbonyl compounds gives the first isolable aldehyde and ketone complexes of zinc as models for transient metal-substrate complexes in metalloenzymes such as liver alcohol dehydrogenase.

引用

页码：1735 / 1737

页数：3

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