THE 1ST STABLE ALDEHYDE AND KETONE COMPLEXES OF ZINC - THE STRUCTURE OF [ZN(SEC6H2BUT3)2(PARA-O=CHC6H4OME)]2

被引：38

作者：

BOCHMANN, M ^{[1
]}

WEBB, KJ ^{[1
]}

HURSTHOUSE, MB ^{[1
]}

MAZID, M ^{[1
]}

机构：

[1] QUEEN MARY & WESTFIELD COLL,DEPT CHEM,LONDON E1 4NS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 24期

关键词：

D O I：

10.1039/c39910001735

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Zn(EC6H2But3)2 (E = S or Se) with organic carbonyl compounds gives the first isolable aldehyde and ketone complexes of zinc as models for transient metal-substrate complexes in metalloenzymes such as liver alcohol dehydrogenase.

引用

页码：1735 / 1737

页数：3

共 29 条

[1] LEWIS ACID COMPLEXES WHICH SHOW SPECTROSCOPIC SIMILARITIES TO AN ALCOHOL-DEHYDROGENASE TERNARY COMPLEX
ANGELIS, CT
DUNN, MF
MUCHMORE, DC
WING, RM
[J]. BIOCHEMISTRY, 1977, 16 (13) : 2922 - 2931
[2] THIOLATO-COMPLEXES OF THE TRANSITION-METALS
BLOWER, PJ
DILWORTH, JR
[J]. COORDINATION CHEMISTRY REVIEWS, 1987, 76 : 121 - 185
[3] STERICALLY HINDERED CHALCOGENOLATO COMPLEXES - MONO-MERIC AND DI-MERIC THIOLATES AND SELENOLATES OF ZINC AND CADMIUM - STRUCTURE OF ((CD(SEC6H2BUT3-2,4,6)2)2), THE 1ST 3-CO-ORDINATE CADMIUM SELENIUM COMPLEX
BOCHMANN, M
WEBB, KJ
HURSTHOUSE, MB
MAZID, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (09): : 2317 - 2323
[4] SYNTHESIS, STRUCTURE, AND GAS-PHASE DECOMPOSITION OF [CD(SC6H2TBU3)2]2 [CD(SEC6H2TBU3)2]2 - 1ST EXAMPLES OF LOW-COORDINATE VOLATILE CADMIUM CHALCOGENOLATO COMPLEXES
BOCHMANN, M
WEBB, K
HARMAN, M
HURSTHOUSE, MB
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (06): : 638 - 639
[5] Bochmann M., 1990, ANGEW CHEM, V102, P703
[6] BOCHMANN M, UNPUB
[7] BRANDEN CI, 1983, CHEM SCRIPTA, V21, P13
[8] CRYSTAL-STRUCTURE DETERMINATIONS OF CO-ENZYME ANALOG AND SUBSTRATE COMPLEXES OF LIVER ALCOHOL-DEHYDROGENASE - BINDING OF 1,4,5,6-TETRAHYDRONICOTINAMIDE ADENINE-DINUCLEOTIDE AND TRANS-4-(N,N-DIMETHYLAMINO)CINNAMALDEHYDE TO THE ENZYME
CEDERGRENZEPPEZAUER, E
SAMAMA, JP
EKLUND, H
[J]. BIOCHEMISTRY, 1982, 21 (20) : 4895 - 4908
[9] CRYSTAL-STRUCTURES OF ZN(SR)2 COMPLEXES - STRUCTURAL MODELS FOR THE PROPOSED [ZN(CYS-S)2(HIS)2] CENTER IN TRANSCRIPTION FACTOR-IIIA AND RELATED NUCLEIC-ACID BINDING-PROTEINS
CORWIN, DT
KOCH, SA
[J]. INORGANIC CHEMISTRY, 1988, 27 (03) : 493 - 496
[10] ZINC, COBALT, AND CADMIUM THIOLATE COMPLEXES - MODELS FOR THE ZINC(S-CYS)2(HIS)2 CENTER IN TRANSCRIPTION FACTOR IIIA (CYS = CYSTEINE HIS = HISTIDINE)
CORWIN, DT
GRUFF, ES
KOCH, SA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (13) : 966 - 967

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