SPECTROPHOTOMETRIC INVESTIGATIONS ON URANIUM(VI) N-(THIOBENZOYL)-N-PHENYLHYDROXYLAMINE COMPLEXES

被引：2

作者：

SHARMA, BK ^{[1
]}

MATHUR, SP ^{[1
]}

DUBEY, SP ^{[1
]}

机构：

[1] UNIV DELHI, COLL CHEM, DELHI 110007, INDIA

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY | 1984年 / A21卷 / 04期

关键词：

D O I：

10.1080/00222338408056558

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

U(VI) forms an intense yellow-colored complex with N-(thiobenzoyl)-N-phenylhydroxylamine. The complex has maximum absorbance at 410 nm at pH 5.1-5.7. Beer''s law is valid up to 29.4 ppm of U(VI). The molar absorptivity is 1.87 .times. 104 mol-1 cm-1. The effects of diverse ions, stability constants and the structure of the complex are discussed.

引用

页码：427 / 430

页数：4

共 16 条

[1] COMPLEX FORMATION BETWEEN ORGANIC THIO-ACIDS AND GERMANIC ACID [J].