KINETICS AND MECHANISM OF OXYGEN-TRANSFER IN THE REACTION OF PARA-CYANO-N,N-DIMETHYLANILINE N-OXIDE WITH METALLOPORPHYRIN SALTS .5. THE INFLUENCE OF IMIDAZOLE LIGATION OF (MESO-TETRAKIS(2,6-DIMETHYLPHENYL)PORPHINATO)MANGANESE(III) CHLORIDE ON THE RATES OF OXYGEN-TRANSFER FROM N-OXIDE TO METALLOPORPHYRIN SALT AND THE EFFICIENCY OF OXIDATIONS BY THE INTERMEDIATE HIGHER VALENT MANGANESE OXO SPECIESI

被引：38

作者：

WONG, WH ^{[1
]}

OSTOVIC, D ^{[1
]}

BRUICE, TC ^{[1
]}

机构：

[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1987年 / 109卷 / 11期

关键词：

D O I：

10.1021/ja00245a039

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：3428 / 3436

页数：9

共 30 条

[1] ON PREPARATION OF METALLOPORPHYRINS [J].

ADLER, AD ;

LONGO, FR ;

KAMPAS, F ;

KIM, J .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1970, 32 (07) :2443-&

[2] A KINETIC-STUDY OF THE EPOXIDATION OF 2,3-DIMETHYL-2-BUTENE BY TERT-BUTYL HYDROPEROXIDE CATALYZED BY IMIDAZOLE LIGATED (MESO-TETRAPHENYLPORPHINATO)MANGANESE(III) [J].

BALASUBRAMANIAN, PN ;

SINHA, A ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (05) :1456-1462

[3] OXYGENATION OF HYDROCARBONS BY CYTOCHROME-P-450 MODEL COMPOUNDS - MODIFICATION OF REACTIVITY BY AXIAL LIGANDS [J].

COLLMAN, JP ;

KODADEK, T ;

RAYBUCK, SA ;

MEUNIER, B .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA-PHYSICAL SCIENCES, 1983, 80 (22) :7039-7041

[4] EPOXIDATION OF OLEFINS BY CYTOCHROME-P-450 MODEL COMPOUNDS - KINETICS AND STEREOCHEMISTRY OF OXYGEN ATOM TRANSFER AND ORIGIN OF SHAPE SELECTIVITY [J].

COLLMAN, JP ;

BRAUMAN, JI ;

MEUNIER, B ;

HAYASHI, T ;

KODADEK, T ;

RAYBUCK, SA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (07) :2000-2005

[5] EPOXIDATION OF OLEFINS BY CYTOCHROME-P-450 MODEL COMPOUNDS - MECHANISM OF OXYGEN ATOM TRANSFER [J].

COLLMAN, JP ;

BRAUMAN, JI ;

MEUNIER, B ;

RAYBUCK, SA ;

KODADEK, T .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA-PHYSICAL SCIENCES, 1984, 81 (10) :3245-3248

[6] KINETICS AND MECHANISMS OF OXYGEN-TRANSFER IN THE REACTION OF PARA-CYANO-N,N-DIMETHYLANILINE N-OXIDE WITH METALLOPORPHYRIN SALTS .2. AMINE OXIDATION AND OXYGEN-TRANSFER TO HYDROCARBON SUBSTRATES ACCOMPANYING THE REACTION OF PARA-CYANO-N,N-DIMETHYLANILINE N-OXIDE WITH MESO-(TETRAPHENYLPORPHINATO)IRON(III) CHLORIDEA [J].

DICKEN, CM ;

LU, FL ;

NEE, MW ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (20) :5776-5789

[7] KINETICS AND MECHANISMS OF OXYGEN-TRANSFER IN THE REACTION OF PARA-CYANO-N,N-DIMETHYLANILINE N-OXIDE WITH METALLOPORPHYRIN SALTS .3. CATALYSIS BY [MESO-TETRAKIS(2,6-DICHLOROPHENYL)PORPHINATO]IRON(III)CHLORIDE [J].

DICKEN, CM ;

WOON, TC ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (07) :1636-1643

[8]

FIESER LF, 1967, REAGENTS ORGANIC SYN, V1, P136

[9]

GUILMET E, 1982, NOUV J CHIM, V6, P511

[10] PRELIMINARY APPROACH TO THE MECHANISM OF THE NAOCL/MN(TPP)OAC EPOXIDATION SYSTEM [J].

GUILMET, E ;

MEUNIER, B .

JOURNAL OF MOLECULAR CATALYSIS, 1984, 23 (01) :115-119

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