ISOSTRUCTURAL POTASSIUM AND SODIUM DI-NITROGEN FUNCTIONALIZED AMIDES - SYNTHESES AND CRYSTAL-STRUCTURES OF [PH(2-PYR)NK.TMEDA]2 AND [ME(2-PYR)NNA.TMEDA]2

被引：24

作者：

ANDREWS, PC

BAKER, DR

MULVEY, RE

CLEGG, W

ONEIL, PA

机构：

[1] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,GLASGOW G1 1XL,SCOTLAND

[2] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

POLYHEDRON | 1991年 / 10卷 / 15期

关键词：

D O I：

10.1016/S0277-5387(00)83809-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two alkali metal amide complexes, [Ph(2-Pyr)NK.TMEDA]2 and [Me(2-Pyr)NNa.TMEDA]2, synthesized from 1:1:1 mixtures of PhM (M = K or Na), the appropriate secondary amine and the Lewis base TMEDA, have been structurally identified by X-ray diffraction and shown to adopt analogous dimeric structures based on planar (N-M)2 rings with additional "internal"- and "external"-donor N.M links that render the metal cations six-coordinate.

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页码：1839 / 1841

页数：3

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