T-SHAPED INTERMOLECULAR CH...PI (C-C) INTERACTIONS IN CHLOROFORM SOLVATES OF GOLD(I) ETHYNE COMPLEXES

被引：80

作者：

MULLER, TE ^{[1
]}

MINGOS, DMP ^{[1
]}

WILLIAMS, DJ ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 15期

关键词：

D O I：

10.1039/c39940001787

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molecular structures of the chloroform solvates of the ethynediyl digold complexes NpPh(2)P-Au-C=C-Au-PNpPh(2).2CHCl(3) 1 (Np = naphthyl) and Np(2)PhP-Au-C=C-Au-PNp(2)Ph.6CHCl(3) 2 have been determined by X-ray techniques; although none of the compounds have short Au...Au contacts compounds 1 and 2 do exhibit novel C-H...pi interactions between the protons of CHCl3 molecules and the pi.electron system of the C=C bond.

引用

页码：1787 / 1788

页数：2

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