KINETICS OF POLYMERIZATION OF METHYL-METHACRYLATE INITIATED WITH CYCLOHEXANONE .1.

被引：9

作者：

KAIM, A

机构：

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1984年 / 22卷 / 08期

关键词：

Catalysts - CHEMICAL REACTIONS - Reaction Kinetics - MONOMERS - Polymerization - Organic compounds - POLYMERIZATION - Catalysis;

D O I：

10.1002/pol.1984.170220811

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The kinetics of radical polymerization of methyl methacrylate were investigated in a dioxane solution with cyclohexanone as initiator. It was found that the overall rate of reaction initiated with cyclohexanone (R//p) is proportional to the concentration of monomer and to the square root of the concentration of the initiator. The effect of temperature on the R//p in the temperature range of 65-95 degree C was discussed. The Arrhenius activation energy E//a estimated for the temperature range of 65-75 degree C was 137 kJ mol** minus **1.

引用

页码：1891 / 1895

页数：5